After update to 24.2.0.3 hitting the print button changes to "save file" and then shows printing not responding with a message "unable to find PDF setting "standard.joboptions". If you choose "use default PDF setting file" no printing starts.
Please test in safe mode, Menu/Help/Restart in Safe Mode
Uli: please come to Bugzilla and leave a comment. Never send private emails. Uli sent me this email: Open attached file PRINT - Preview shows - PRINT Message: Save PDF file as SAVE Message: Unable to find PDF setting file Attached was an .ods file. I used Microsoft PDF printer and it worked fine. Uli: please respond how it works in Safe Mode. Version: 24.2.0.3 (X86_64) / LibreOffice Community Build ID: da48488a73ddd66ea24cf16bbc4f7b9c08e9bea1 CPU threads: 2; OS: Windows 10.0 Build 22621; UI render: Skia/Raster; VCL: win Locale: en-US (en_US); UI: en-US Calc: threaded